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Structural Studies of Crystalline Pentacalent Organobismuth Compounds |
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| Authors: | Derek H R Barton Brigitte Charpiot Elise Tran Huu Dau William B Motherwell Claudine Pascard Clotilde Pichon |
| Abstract: | The syntheses and X-Ray analyses of three pentavalent organobismuth compounds are described; one of these compounds has a novel diphenylbis(trifluoroacetato)-bismuthate anion with trigonal bipyramidal geometry and a stereochemically active lone pair. Analysis of these structures together with other data from the literature allows a mapping of the reaction coordinate for bismuth polyhedra. |
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