Abstract: | 29Si-NMR Chemical Shift of Compounds with Four Electronegative Substituents at Silicon The influence of the d-orbitals of IIIrd row elements and also the inductive and steric effects of the organoxy groups on the 29Si-NMR chemical shift of compounds with four electronegative substituents attached to silicon wer evaluated. A bridging effect on the transmission of the inductive effects over the oxygen atom which is bonded with silicon was stated. |