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Reactions of 3, 5-Dimethyl-4-Carbethoxy-2-Cyclohexen-1-One at α-Position
Authors:A U Rahman  M Y Khan
Abstract:3, 5-Dimethyl-4-carbethoxy-2-cyclohexen-1-one has been synthesized through the Knoevenagel condensation1, which is then subjected to alkylation and acylation at α-position. The resulting products are hydrolyzed and decarboxylated to α-substituted cyclohexenones. 3, 5-Dimethyl-2-cyclohexen-1-one is converted by N-bromosuccinimide to phenol via enolization2.
Keywords:α  -substituted alkylation and acylation to α    β  -unsaturated cyclic ketoester
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