Gas phase reactions of CF3, C2F5, and n-C3F7 with carbon tetrachloride |
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| Authors: | C. M. de V hringer,E. H. Staricco |
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| Affiliation: | C. M. de Vöhringer,E. H. Staricco |
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| Abstract: | The reactions of some perfluoroalkyl radicals with carbon tetrachloride have been studied using the photolysis of the corresponding perfluoroalkyl iodide as the free radical source. The Arrhenius parameters, based on the value of 2.3 × 1013 cm3 mol?1 s?1 for the self-combination rate constant of all radicals are: | Reaction | log(A/cm3 mol?1 s?1) | E/kcal mol?1 | | CF3 + CCl4 | 12.8 | 11.3 | | C2F5 + CCl4 | 12.8 | 11.6 | | n-C3F7 + CCl4 | 12.9 | 12.0 |  Volume 16 , Issue 11 November 1984 Pages 1351-1356 |
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