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Green Oxidations. Manganese(II) Sulfate Aided Oxidations of Organic Compounds by Potassium Permanganate
Authors:Ahmad Shaabani  Abbas Rahmati  Masoumeh Sharifi  Jafar Mogimi Rad  Behnaz Aghaaliakbari  Elham Farhangi  Donald G. Lee
Affiliation:(1) Department of Chemistry, Shahid Beheshti University, Tehran, Iran;(2) Department of Chemistry, University of Kashan, Kashan, Iran;(3) Department of Chemistry and Biochemistry, University of Regina, Regina, SK, Canada
Abstract:Summary. The oxidation of arenes and sulfides by potassium permanganate was accomplished in good yields under solvent free and heterogeneous conditions when manganese(II) sulfate is used as a solid support. After extraction of the organic products, the inorganic products can be reoxidized to permanganate. This result is important because it provides an approach to oxidation reactions that is, in theory, infinitely sustainable.
Keywords:. Oxidation   Solvent free   Permanganate   Arene   Sulfide.
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