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载铂微粒的聚苯胺薄膜电极对甲醇的电催化氧化
引用本文:吴婉群 万本强. 载铂微粒的聚苯胺薄膜电极对甲醇的电催化氧化[J]. 应用化学, 1994, 11(2): 40-43
作者姓名:吴婉群 万本强
作者单位:西南师范大学化学系
基金项目:国家自然科学基金资助课题
摘    要:用电化学方法制备的载有金属铂微粒的聚苯胺(PAn)膜电极对甲醇在硫酸中的电化学氧化具有很高的催化活性。电极材料中的铂微粒是沿着聚苯胺的纤维分布的,而且主要沉积在PAn膜的表面。

关 键 词:甲醇,电催化氧化,聚苯胺,铂微粒
收稿时间:1993-07-12

Electrocatalytic Oxidation of Methanol at Polyaniline Film Electrode with Platinum Microparticles
Wu Wanqun,Wan Benqiang,Luo Weizhong. Electrocatalytic Oxidation of Methanol at Polyaniline Film Electrode with Platinum Microparticles[J]. Chinese Journal of Applied Chemistry, 1994, 11(2): 40-43
Authors:Wu Wanqun  Wan Benqiang  Luo Weizhong
Abstract:The polyaniline film electrodes with platinum microparticles were prepared byelectrochemical method.The morphology of the electrode was examined by scanning electronmicroscopy. Oxidation of methanol in 0.5mol/L H_2SO_4 indicated that the platinum micropar-ticles were dispersed in a three-dimensional array in polyaniline film,mainly loaded on thesurface of polyaniline film. A very high electrocatalytic activity in oxidation of methanol in0.5mol/L H_2SO_4 was found.The catalytic current was much higher than that obtained onthe bare platinum and polyaniline film electrode.
Keywords:methanol   electrocatalytic oxidation    polyaniline    platinum microparticle
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