pH-Induced formation of metalloligand: increasing structure dimensionality by tuning number of ligand functional sites |
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Authors: | Ni Wen-Xiu Li Mian Zhou Xiao-Ping Li Zhen Huang Xiao-Chun Li Dan |
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Institution: | Department of Chemistry, Shantou University, Guangdong, 515063, PR China. |
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Abstract: | Two complexes, 2D Cu(2)(CN)(2)(4-Hpcih)](n) and 3D Cu(2)(CN)(1.5)(4-pcih)].1.25H(2)O](n) (4-Hpcih = 4-pyridinecarbaldehyde isonicotinoyl hydrazone), were obtained using a synthetic approach of pH-induced formation of metalloligands, successfully demonstrating a strategy to increase structure dimensionality by tuning the number of ligand functional sites. |
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