NMR Study of Reactions between Pd,Ru, and Rh Nitrite Complexes with Sulfamic Acid |
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| Authors: | Belyaev A. V. Emel'yanov V. A. Khranenko S. P. Fedotov M. A. |
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| Affiliation: | (1) Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russia |
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| Abstract: | Reactions of nitrite complexes of Pd, Ru, and Rh with sulfamic acid were studied by the 14, 15N, and 17O NMR method. Chemical shifts were assigned, and the predominant forms of the complexes were established. The reaction products at room temperature are cis-nitroaqua complexes. Coordination of the sulfamate ion upon storage for a long time or on heating was detected. |
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