Luminescence characteristics and X‐ray crystal structure of [Cd(bipy)3][PF6]2 (bipy = 2,2′‐bipyridine) |
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| Authors: | Nabanita Kundu Debdas Mandal Muktimoy Chaudhury Edward R. T. Tiekink |
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| Abstract: | The photoluminescence characteristics of the [Cd(bipy)3][PF6]2 complex are reported. A moderately large quantum yield (φ) of 1.07 × 10?2 is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by C? H···π and C? H···F interactions. Copyright © 2005 John Wiley & Sons, Ltd. |
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| Keywords: | cadmium(II) 2,2′ ‐bipyridine luminescence crystal structure |
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