| Abstract: | The synthesis and structural characterization of new liquid‐crystalline compounds containing ferrocene, azo‐aromatic and cholesteryl groups are reported. Taking into account the advantage brought by chirality, ferrocene and azo units, these structures could be good precursors for obtaining materials capable of responding to magnetic and electric fields or to UV‐light exposure. The influence of each structural unit (ferrocene, cholesterol, azo aromatic core and flexible chain length) has been studied by comparing analogous compounds possessing the same structure but without the element being analyzed. Ferrocene is a three‐dimensional bulky unit, so that, regardless of the substituents' nature, this unit could cause steric repulsions with neighboring molecules. These interactions could lead to a decrease of the transition temperature domain. Surprisingly, a decrease in the clearing point was not observed for the compounds discussed. This behavior was possible because ferrocene is connected to the mesogen via a flexible unit. As a consequence, both phenyl analogues and ferrocene derivatives presented liquid‐crystalline properties with similarly high clearing points, but above the thermal stability of derivatives with azo groups. Their melting points depend on the way the molecules are packed, with different crystalline states being detected in the case of ferrocene derivatives. In order to explain the liquid‐crystalline behavior of the compounds synthesized, molecular simulations were performed using the Hyperchem program. Copyright © 2005 John Wiley & Sons, Ltd. |
