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Utilization of organogallium and organoindium compounds as alkylation reagents in organic synthesis: the addition of trialkylgallium and trialkylindium to aldehydes catalyzed by Lewis acids |
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| Authors: | Zhenya Dai Mingran Shao Xianshan Hou Chengjian Zhu Yuhua Zhu Yi Pan |
| Abstract: | The utilization of organogallium and organoindium compounds as alkylation reagents to aldehydes was realized with titanium tetrachloride as the strong Lewis acid catalyst. Furthermore, the catalytic asymmetric addition of organogallium to aldehydes was investigated with chiral titanium complexes, which were formed from titanium tetrachloride and salan ligands, with mediocre to good chemical yields and enantioselectivities. Copyright © 2005 John Wiley & Sons, Ltd. |
| Keywords: | organogallium organoindium aldehydes Lewis acid asymmetric catalysis chiral Lewis acid |