Polymer Solar Cells Based on a Low‐Bandgap Fluorene Copolymer and a Fullerene Derivative with Photocurrent Extended to 850 nm |
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Authors: | F Zhang E Perzon X Wang W Mammo MR Andersson O Ingans |
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Institution: | F. Zhang,E. Perzon,X. Wang,W. Mammo,M.?R. Andersson,O. Inganäs |
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Abstract: | Polymer solar cells have been fabricated from a recently synthesized low band‐gap alternating polyfluorene copolymer, APFO‐Green2, combined with 6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) from organic solutions. External quantum efficiencies (EQEs) of the solar cells show an onset at 850 nm and a peak of > 10 % located at 650 nm, which corresponds to the extended absorption spectrum of the polymer. Photocurrent of 3.0 mA cm–2, photovoltage of 0.78 V, and power conversion efficiency of 0.9 % have been achieved in solar cells based on this new low‐bandgap polymer under the illumination of air mass 1.5 (AM 1.5) (1000 W m–2) from a solar simulator. |
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Keywords: | Fullerenes Organic– inorganic hybrid materials Polyfluorenes Solar cells polymer |
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