Binuclear zinc naphthoate complex with 1,10-phenanthroline: synthesis,structure, and photoluminescence properties |
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| Authors: | Goldberg A E Kiskin M A Kozyukhin S A Sidorov A A Eremenko I L |
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| Institution: | 1.N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation
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| Abstract: | The new binuclear complex (1,10-phen)2Zn2(μ2-OOCR)2(η2-OOCR)2]·4THF (2·4THF, RCOO− is the β-naphthoate anion) was synthesized. According to the single-crystal X-ray diffraction study, a one-dimensional supramolecular
structure is formed through intra- and intermolecular π-π interactions between the phenanthroline moieties of complex 2. Compound 2 exhibits photoluminescence properties at room temperature. |
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