Metal-metal bond formation between [n]metallocenophanes: synthesis and characterisation of a dicarba[2]ruthenocenophanium dimer |
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| Authors: | Russell Andrew D Gilroy Joe B Lam Kevin Haddow Mairi F Harvey Jeremy N Geiger William E Manners Ian |
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| Affiliation: | School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK. |
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| Abstract: | Feeling the strain: The first example of metal-metal bonding between strained [n]metallocenophanes is reported. A dicarba[2]ruthenocenophanium dimer has been synthesised through the oxidation of a dicarba[2]ruthenocenophane (see figure). The structural and electrochemical characterisation of the dimer is also discussed. |
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