| STUDIES ON BIPYRIDINIUM SALTS AND THEIR POLYMERS Ⅰ. SYNTHESIS OF 4, 4''-(1, 4-PHENYLENE-)BIS-[N-ALKYL (ARYL)-2, 6-DIPHENYL-] PYRIDINIUM SALTS AND THEIR POLYMERS FROM CORRESPONDING BIPYRYLIUM SALT* |
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| 引用本文： | 杨玉崑. STUDIES ON BIPYRIDINIUM SALTS AND THEIR POLYMERS Ⅰ. SYNTHESIS OF 4, 4''-(1, 4-PHENYLENE-)BIS-[N-ALKYL (ARYL)-2, 6-DIPHENYL-] PYRIDINIUM SALTS AND THEIR POLYMERS FROM CORRESPONDING BIPYRYLIUM SALT*[J]. 高分子科学, 1985, 0(3): 185-193 |
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| 作者姓名： | 杨玉崑 |
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| 作者单位： | Insitute of |
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| 摘 要： | The reaction of pyrylium salt with primary amine has been utilized to synthesize 4,4'-bipyri-dinium salts and pyridinium polymers. Seven new 4,4'-(1,4-phenylene-) bis-[N-alkyl(aryl)-2,6-diphenyl-] pyridinium perchlorates 4 and five corresponding bipyridinium polymers 5 were preparedwith good yields from 4,4'-(1,4-phenylene-) bis-(2,6-diphenyl-) pyrylium perchlorate 3. Preliminarytests have been made for their redox behavior and catalytic activity.
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| 收稿时间： | 1985-01-26 |
STUDIES ON BIPYRIDINIUM SALTS AND THEIR POLYMERS Ⅰ. SYNTHESIS OF 4, 4'-(1, 4-PHENYLENE-)BIS-[N-ALKYL (ARYL)-2, 6-DIPHENYL-] PYRIDINIUM SALTS AND THEIR POLYMERS FROM CORRESPONDING BIPYRYLIUM SALT* |
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| YANG Yukun. STUDIES ON BIPYRIDINIUM SALTS AND THEIR POLYMERS Ⅰ. SYNTHESIS OF 4, 4'-(1, 4-PHENYLENE-)BIS-[N-ALKYL (ARYL)-2, 6-DIPHENYL-] PYRIDINIUM SALTS AND THEIR POLYMERS FROM CORRESPONDING BIPYRYLIUM SALT*[J]. Chinese Journal of Polymer Science, 1985, 0(3): 185-193 |
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| Authors: | YANG Yukun |
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| Affiliation: | Institute of Chemistry; Academia Sinica; Beijing |
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| Abstract: | The reaction of pyrylium salt with primary amine has been utilized to synthesize 4,4'-bipyri-dinium salts and pyridinium polymers. Seven new 4,4'-(1,4-phenylene-) bis-[N-alkyl(aryl)-2,6-diphenyl-] pyridinium perchlorates 4 and five corresponding bipyridinium polymers 5 were preparedwith good yields from 4,4'-(1,4-phenylene-) bis-(2,6-diphenyl-) pyrylium perchlorate 3. Preliminarytests have been made for their redox behavior and catalytic activity. |
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