| 草酰胺配体的微波合成 |
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| 引用本文： | 李选,陈晓影,袁荞龙,张丹枫,黄葆同.草酰胺配体的微波合成[J].有机化学,2006,26(8):1100-1102. |
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| 作者姓名： | 李选 陈晓影 袁荞龙 张丹枫 黄葆同 |
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| 作者单位： | 1. 华东理工大学材料科学与工程学院,上海,200237
2. 华东理工大学材料科学与工程学院,上海,200237;中国科学院长春应用化学研究所,长春,130022 |
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| 摘 要： | 在微波辐照下, 分别由苯胺、取代苯胺和草酸通过无溶剂法反应, 合成出N,N′-二(苯基)草酸二酰胺和N,N′-二(取代苯基)草酸二酰胺, 利用1H NMR, MS和元素分析对其结构进行了表征. 研究表明, 增加辐照功率选择合适的辐照时间有利于产物收率的提高, 甲基或氯单取代的苯胺得率高于苯胺, 增加固液两相的接触面积可大大提高产物的收率.
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| 关 键 词： | 微波辐照 草酸 取代苯胺 N N′-二取代草酸二酰胺 |
| 收稿时间： | 08 3 2005 12:00AM |
| 修稿时间： | 02 8 2006 12:00AM |
Microwave Synthesis of Oxamide Ligands |
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| LI, Xuan,CHEN, Xiao-Ying,YUAN, Qiao-Long,ZHANG, Dan-Feng,HUANG, Bao-Tong.Microwave Synthesis of Oxamide Ligands[J].Chinese Journal of Organic Chemistry,2006,26(8):1100-1102. |
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| Authors: | LI Xuan CHEN Xiao-Ying YUAN Qiao-Long ZHANG Dan-Feng HUANG Bao-Tong |
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| Institution: | 1. School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237;2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 |
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| Abstract: | N,N′-Bis(phenyl)oxamide and N,N′-bis(substituted phenyl)oxamides were synthesized from aniline, substituted anilines and oxalic acid under microwave irradiation in solvent-free. These compounds were identified by 1H NMR, MS spectra and elemental analysis. The results showed that the product yield was increased by increase of irradiation power and option of appropriate irradiation time. The methyl or chloro substituted anilines were useful to increase the product yield than aniline, and the product yield was enhanced largely by increase of interface between solid and liquid. |
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| Keywords: | microwave irradiation oxalic acid subsitituted aniline N N′-bis(substituted phenyl)oxamide |
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