Synthesis and molecular and crystal structure oftrans-{bis(4,6-diisopropyl-2,5-diphenyl-1,3,2,5-dioxaboraphosphorinane)} dichloroplatinum(II) |
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| Authors: | A A Karasik G N Nikonov I A Litvinov |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation |
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| Abstract: | Thetrans-{bis(4,6-diisopropyl-2,5-diphenyl-1,3,2,5-dioxaboraphosphorinane)}dichloroplatinum(II) complex was obtained by the interaction of 4,6-diisopropyl-2,5-diphenyl-1,3,2,5-dioxaboraphosphorinane with bis(benzonitrile)dichloroplatinum(II). In solution this complex occurs as a mixture of isomers. X-ray analysis revealed close contacts between the platinum atom and one oxygen atom of the ligands.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1040–1043, June, 1993. |
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| Keywords: | complex (dioxaboraphosphorinane)dichloroplatinum(II) stereoisomers |
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