Spectral studies of copper(II) complexes of tridentate acylhydrazone ligands with heterocyclic compounds as coligands: X-ray crystal structure of one acylhydrazone copper(II) complex |
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Authors: | Mathew Nancy Sithambaresan Maheswaran Kurup M R Prathapachandra |
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Institution: | Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682022, Kerala, India. |
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Abstract: | Six copper(II) complexes of 2-hydroxy-4-methoxybenzaldehyde nicotinoylhydrazone (H2hmbn), 2-hydroxy-4-methoxyacetophenone nicotinoylhydrazone (H2hman), 2-hydroxy-4-methoxybenzaldehyde benzoylhydrazone (H2hmbb) and 2-hydroxy-4-methoxyacetophenone benzoylhydrazone (H2hmab) have been synthesized. The complexes viz. Cu(hmbn)](2)·2H(2)O (1), Cu(hman)](2) (2), Cu(hmbb)](2)·2H(2)O (3), Cu(hmbb)phen]·1(1/2)H2O (4), Cu(hmbb)(bipy)·H2O] (5) and Cu(hmab)phen] (6) were characterized by different physicochemical techniques. The crystal structure of Cu(hman)phen] is obtained and it has a distorted square pyramidal geometry with π-π stacking interactions and significant C-H π interactions. |
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