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New methods applicable for calibration of indicator electrodes |
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| Authors: | Michałowski Tadeusz Pilarski Bogusław Ponikvar-Svet Maja Asuero Agustin G Kukwa Agata Młodzianowski Janusz |
| Institution: | a Faculty of Chemical Engineering and Technology, Cracow University of Technology, Cracow, Poland b P.P.H.U. Cerko s.c., Afrodyty 9, 80-299 Gdańsk, Poland c Department of Inorganic Chemistry and Technology, Jo?ef Stefan Institute, Jamova 39, Ljubljana, Slovenia d Department of Analytical Chemistry, The University of Seville, 41012 Seville, Spain |
| Abstract: | The new methods applicable for calibration of indicator electrodes, based on standard addition and standard subtraction methods, are suggested. Some of the methods enable the slope of an indicator electrode and equivalence volume Veq to be determined simultaneously from a single set of potentiometric titration data. Some other methods known hitherto were also taken into account. A new model, based on a standard addition method, applicable also in nonlinear range for the ISE slope (S) is suggested, and its applicability was confirmed experimentally in calibration of calcium ISE. |
| Keywords: | Calibration Indicator electrodes Standard subtraction Standard addition |
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