A triarylboron-based fluorescent thermometer: sensitive over a wide temperature range |
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| Authors: | Feng Jiao Tian Kaijun Hu Dehui Wang Shuangqing Li Shayu Zeng Yi Li Yi Yang Guoqiang |
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| Affiliation: | Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, China. |
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| Abstract: | Feeling blue: the luminescence of a triarylboron compound has a high quantum yield (at least 0.64) over a wide temperature range (-50 to +100 °C) and changes from green to blue as the temperature is increased. The luminescence color was determined by the population of the two distinct excited-state conformations-a local excited state (high temperature) and a twisted intramolecular charge-transfer state (low temperature). |
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| Keywords: | fluorescence photochemistry thermochromism triarylboron compounds |
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