| 杯[4]芳烃固定相分离芳香族位置异构体的热力学特性研究 |
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| 引用本文： | 王建玲,候学会,王国庆,吕全建.杯[4]芳烃固定相分离芳香族位置异构体的热力学特性研究[J].河南科学,2011,29(11):1305-1308. |
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| 作者姓名： | 王建玲 候学会 王国庆 吕全建 |
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| 作者单位： | 1. 郑州牧业工程高等专科学校质量检测与管理系,郑州,450008
2. 郑州轻工业学院应用化学系,郑州,450002 |
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| 基金项目： | 国家自然科学基金(20675073) |
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| 摘 要： | 将双十一碳烯氧基杯4]芳烃冠醚聚硅氧烷(C4]C5-PSO)和上缘稀基取代杯4]芳烃四苄基醚聚硅氧烷(C4]TBE-PSO)用作毛细管气相色谱固定相,通过测定一些芳香族位置异构体在2种固定相上的热力学参数△H、△S和△G,探讨了杯4]芳烃衍生物气相色谱固定相对芳香族位置异构体分子识别的特性和保留机理.
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| 关 键 词： | 杯[4]芳烃 固定相 芳香族化合物 热力学参数 |
Thermodynamics Characteristic on the Separation of Aromatic Positional Isomers by the Stationary Phases of Calix[4] Arene |
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| Wang Jianling,Hou Xuehui,Wang Guoqing,LV Quanjian.Thermodynamics Characteristic on the Separation of Aromatic Positional Isomers by the Stationary Phases of Calix[4] Arene[J].Henan Science,2011,29(11):1305-1308. |
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| Authors: | Wang Jianling Hou Xuehui Wang Guoqing LV Quanjian |
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| Institution: | Wang Jianling1,Hou Xuehui1,Wang Guoqing2,LV Quanjian1 (1.Zhengzhou College of Animal Husbandry Engineering,Quality Monitoring and Management,Zhengzhou 450008,China,2.Zhengzhou Institute of Light Industry,Department of Applied Chemistry,Zhengzhou 450002,China) |
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| Abstract: | Two kinds of calix4] arene functionalized(C4]C5-PSO and C4]TBE-PSO) were used as the stationary phases for capillary gas chromatography.The kinds of calix4] arene functionalized were found to have unique selectivity for positional isomers of aromatic compounds.Thermodynamic parameters(△H,△S and △G) of these compounds were gained on two stationry phases.Molecular recognition and resolution mechanism about calix4] arene functionalized were discussed form thermodynamic characteristics. |
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| Keywords: | cailic[4] arene stationary phase aromatic compounds thermodynamic parameters |
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