| 单纯形-偏差图形识别法在极谱吸附波研究中的应用 |
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| 引用本文： | 张正奇,俞汝勤. 单纯形-偏差图形识别法在极谱吸附波研究中的应用[J]. 高等学校化学学报, 1990, 11(3): 250 |
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| 作者姓名： | 张正奇 俞汝勤 |
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| 作者单位： | 湖南大学化学化工系 |
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| 摘 要： | 本文提出了单纯形-偏差图形识别法,并用此方法确定了2-QADNm和2,7-TADN在汞电极上的吸附服从Frumkin吸附等温线,测定了有关参数。
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| 关 键 词： | 单纯形法 偏差图形识别 2-QADNm 2 7-TADN |
| 收稿时间： | 1988-09-17 |
Application of Simplex-Deviation-Pattern Recognition to Studies of Adsorptive Polarographic Wave |
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| Zhang Zhengqi,Yu Ruqin. Application of Simplex-Deviation-Pattern Recognition to Studies of Adsorptive Polarographic Wave[J]. Chemical Research In Chinese Universities, 1990, 11(3): 250 |
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| Authors: | Zhang Zhengqi Yu Ruqin |
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| Affiliation: | Department of Chemistry and Chemical Engineering, Hunan University, Changsha |
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| Abstract: | In this paper the simplex-deviation-pattern recognition is proposed and applied to the studies of adsorptive polarographic wave. With simplex-deviation-pattern recognition it is estimated that the adsorption of 2-QADNm and 2,7-TADN obeys Frumkin isotherm. The values of adsorption coefficient, interaction coefficient between adsorbant molecules and adsorption free energy were determined. |
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| Keywords: | Simplex Deviation-pattern recognition 2-QADNm 2 7-TADN |
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