A catalytically active,charge-neutral Rh(I) zwitterion featuring a P,N-substituted "naked" indenide ligand |
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| Authors: | Stradiotto Mark Cipot Judy McDonald Robert |
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| Affiliation: | Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3. mark.stradiotto@dal.ca |
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| Abstract: | The synthesis and characterization of a new class of cationic and zwitterionic Rh(I) complexes, which feature multidentate ligands comprised of donor-functionalized indene or indenide units, are reported. This unusual new ligation strategy provides access to the first charge-neutral [kappa2-P,N]Rh(I) zwitterion, a complex that functions as a catalyst for the C-H/Si-H dehydrogenative coupling of styrene and triethylsilane. |
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