| The Crystal Structure of 1, 4, 7, 10- Tetraazacyclododecane Hydrate Triperchlorate |
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| 引用本文： | KONG De-Yuan, XIE Yu-Yuan, ZHU Qin ,XIE Yu-Li(Shanghai Institute of Material Medica,the Chinese Academy of Sciences,No. 294,Taiyuan Road,Shanghai 200031,China)HUANG Xiao-Ying(Fujian Institute of Research on the Structure of Matter,the Chinese Academy. The Crystal Structure of 1, 4, 7, 10- Tetraazacyclododecane Hydrate Triperchlorate[J]. 结构化学, 1998, 0(4) |
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| 作者姓名： | KONG De-Yuan XIE Yu-Yuan ZHU Qin XIE Yu-Li(Shanghai Institute of Material Medica the Chinese Academy of Sciences No. 294 Taiyuan Road Shanghai 200031 China)HUANG Xiao-Ying(Fujian Institute of Research on the Structure of Matter the Chinese Academy |
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| 作者单位： | KONG De-Yuan; XIE Yu-Yuan; ZHU Qin ;XIE Yu-Li(Shanghai Institute of Material Medica，the Chinese Academy of Sciences，No. 294，Taiyuan Road，Shanghai 200031，China |
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| 摘 要： | 1=mTRODUCTIONMacroazacyclicligandisofwideinterestbecauseofitsstructuralsimilaritywiththeskeletonofPOrphyrinringinsomebibectivesubstancessuchaschlorophyllandhemeetc.tl1.Asametalsimulationenzyme,macroazacyclicligandcoordinatedwithtransitionmetalhasbeeninvestigatedthoroghlyinkinetic,dynamicandstructuralcharactert2.3).Butthere'isnorePOrtaboutthecrystalstructureof1,4,7,1o-tetraaza-cyclododecanehydratetriperchlorate.2EXPERIMENTAL2-lSynthesisoftheTitleComplexTetraazacycldodecanewassynthes…
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The Crystal Structure of 1, 4, 7, 10- Tetraazacyclododecane Hydrate Triperchlorate |
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| KONG De-Yuan, XIE Yu-Yuan, ZHU Qin ,XIE Yu-Li. The Crystal Structure of 1, 4, 7, 10- Tetraazacyclododecane Hydrate Triperchlorate[J]. Chinese Journal of Structural Chemistry, 1998, 0(4) |
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| Authors: | KONG De-Yuan XIE Yu-Yuan ZHU Qin XIE Yu-Li |
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| Abstract: | The title complex [(C8H23N4)3+ (ClO4)3-]. H2O was crystallized intriclinic system, P1 space group with unite cell parameters: a= 8. 386(2), b= 10. 558(2), c=11. 865(3) A, a= 77. 75(2)' β= 72. 65(2),γ= 74. 77(2)°, V= 957. 3(4)A3, Z= 2, Dc= 1. 706 g/cm3, M,=491. 66, F(000) = 512, μ(MoKa) =5. 49cm-1,=0. 71069 (graphite- monochromated), T = 296K. The title complex is composed ofone [C8H23N4]3+ cation, three ClO4 ions and one crystal water molecule. The final Rand Rw values are 0. 058 and 0. 068 respectively. |
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| Keywords: | crystal structure tetraazacyclododecane perchlorate hydrate |
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