| 4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶芳炔铂(II)络合物的合成及光物理性质 |
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| 引用本文： | 韩雪,吴骊珠,吴梓新,张丽萍,佟振合. 4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶芳炔铂(II)络合物的合成及光物理性质[J]. 影像科学与光化学, 2006, 24(3) |
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| 作者姓名： | 韩雪 吴骊珠 吴梓新 张丽萍 佟振合 |
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| 基金项目： | 国家重点基础研究发展计划(973计划);中国科学院资助项目;中国科学院基础局资助项目 |
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| 摘 要： | 设计合成以4-甲基苯基-6-苯基-2,2′-二联吡啶为主配体、芳炔为辅助配体的铂(II)络合物1-3.与苯乙炔、萘乙炔为辅助配体的络合物1,2相比,蒽乙炔4-(4-甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物MLCT激发态的能量升高.
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| 关 键 词： | 多吡啶铂(II)络合物 芳炔 MLCT激发态 |
The Synthesis and Photophysical Properties of 4-(4-Tolyl-6-Phenyl-2, 2'-Bipyridyl) Platinum(Ⅱ) Aryl-Substituted Acetylide Complexes |
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| HAN Xue,WU Li-zhu,WU Zi-xin,ZHANG Li-ping,TONG Zhen-he. The Synthesis and Photophysical Properties of 4-(4-Tolyl-6-Phenyl-2, 2'-Bipyridyl) Platinum(Ⅱ) Aryl-Substituted Acetylide Complexes[J]. Imaging Science and Photochemistry, 2006, 24(3) |
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| Authors: | HAN Xue WU Li-zhu WU Zi-xin ZHANG Li-ping TONG Zhen-he |
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| Abstract: | 4-(4-tolyl)-6-phenyl-2,2′-bipyridylplatinum(II) aryl-substituted acetylide complexes 1-3 were designed and synthesized.In contrast to complexes 1 and 2,when 9-acetylide-anthracene is employed as ancillary ligand,the energy of lowest emissive excited state of complex 3 increases. |
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| Keywords: | polypyridyl platinum complexes arylacetylene MLCT excited state |
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