| 纳米石墨薄片/聚吡咯复合材料的制备及导电性能 |
| |
| 引用本文： | 莫尊理,左丹丹,陈红,孙银霞,张平.纳米石墨薄片/聚吡咯复合材料的制备及导电性能[J].无机化学学报,2007,23(2):265-269. |
| |
| 作者姓名： | 莫尊理 左丹丹 陈红 孙银霞 张平 |
| |
| 作者单位： | 甘肃省高分子材料重点实验室,西北师范大学化学化工学院,兰州,730070 |
| |
| 基金项目： | 甘肃省科技攻关项目;甘肃省自然科学基金;高等学校博士学科点专项科研项目 |
| |
| 摘 要： | 膨胀石墨经过超声处理制备了纳米石墨薄片。以其为导电填料，对甲苯磺酸为掺杂剂，FeCl3·6H2O为氧化剂，引发吡咯单体发生原位聚合，制备出纳米石墨薄片/聚吡咯(NanoGs/PPy)复合材料。利用红外光谱(FTIR)、扫描电镜(SEM)和透射电镜(TEM)表征了材料的组成和结构。结果表明，石墨薄片被聚吡咯完全包覆；并且以纳米级尺寸分散在聚吡咯基体中。热失重(TG)分析和电导率测试结果表明，复合材料的耐热性能和导电性能较纯聚吡咯有所提高。
|
| 关 键 词： | 纳米石墨薄片 聚吡咯 纳米复合材料 |
| 文章编号： | 1001-4861（2007）02-0265-05 |
| 修稿时间： | 2006-09-22 |
Synthesis and Conductivity of Graphite Nanosheets/Polypyrrole Composites |
| |
| MO Zun-Li,ZUO Dan-Dan,CHEN Hong,SUN Yin-Xia and ZHANG Ping.Synthesis and Conductivity of Graphite Nanosheets/Polypyrrole Composites[J].Chinese Journal of Inorganic Chemistry,2007,23(2):265-269. |
| |
| Authors: | MO Zun-Li ZUO Dan-Dan CHEN Hong SUN Yin-Xia and ZHANG Ping |
| |
| Institution: | Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070,Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070,Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070,Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070 and Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070 |
| |
| Abstract: | Graphite nanosheets (NanoGs) were prepared by treating the expanded graphite with sonication in aqueous alcohol solution. The graphite nanosheets/polypyrrole (NanoGs/PPy) composites were fabricated via in situ polymerization of pyrrole monomer in the presence of NanoGs, using p-toluene-sulfonic acid and FeCl3·6H2O as dopant and oxidant, respectively. The structure of nanocomposites was characterized by FTIR, SEM and TEM. The results show that NanoGs are embedded in PPy matrix, and the dispersion of graphite sheets is in nanoscale. The thermal stability and electrical conductivity of NanoGs/PPy nanocomposites are superior to pure PPy as shown by TG analysis and electrical conductivity test. |
| |
| Keywords: | graphite nanosheet polypyrrole nanocomposite |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
