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Optical switching and alignment of antiferroelectric liquid crystals containing an azo group
Authors:Koichiro Shirota  Ichirou Yamaguchi  Kiyoshi Kanie  Tomiki Ikeda  Tamejiro Hiyama  Ichiro Kobayashi
Affiliation:1. Chemistry Department , Duke University , Durham NC 27708‐0354, USA E-mail: cifjepa@duke.edu cifjepa@duke.edu
Abstract:The optical properties of two kinds of photochromic antiferroelectric liquid crystal (AFLC) containing an azo group have been examined. Depending on the substituting group at the chiral centre, these AFLCs showed different photoinduced phase transitions by Ar+ laser light irradiation. This phase transition has led to a new form of optical switching controlled by a bias voltage. In addition, it was found that these AFLCs caused an azimuthal photoalignment effect regulated by linearly polarized Ar+ laser light irradiation. These phenomena were applied to image storage.
Keywords:biaxial nematics  statistical model  mixing and phase separation  micelle form
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