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The synthesis of low melting liquid crystalline lanthanide complexes with triflate counter-anions
Authors:Francoise Martin  Simon R. Collinson  Duncan W. Bruce
Affiliation:Department of Theoretical Mechanics , University of Nottingham , University Park, Nottingham, NG7 2RD, England
Abstract:Paramagnetic liquid crystalline complexes of the formula [LnL(LH)2][CF3SO3]2 have been synthesised, where LH is the ligand N-dodecyl-4-(3',4'-didodecyloxybenzoyloxy)salicylaldimine and Ln is a lanthanide metal. When compared with analogous nitrate complexes, the transition temperatures are rather low.
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