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Determination of symmetry and molecular arrangements of free-standing liquid crystal films using null-transmission ellipsometry
Authors:D A Olson  X F Han  P M Johnson  A Cady  C C Huang
Institution:1. Department of Chemistry , Nankai University , Tianjin, China hanjie@nankai.edu.cn;3. Department of Chemistry , Nankai University , Tianjin, China
Abstract:A high resolution null-transmission ellipsometry system has been developed for measurement of the optical properties of liquid crystal free-standing films. The ellipsometric parameters are measured to within a resolution of 0.002° from samples held in a sealed, temperature-controlled environment. By measuring the ellipsometric parameters as a function of applied electric field orientation, the optical symmetry and molecular orientations of free-standing liquid crystal films can be determined in some cases. Three carefully selected applications of this technique are presented.
Keywords:heterocyclic liquid crystal  spectroscopic property  cholesteric mesophase  synthesis
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