Comparison of liquid crystalline properties of dimeric compounds of different skeletal shapes

Series of dimeric compounds of different skeletal shapes consisting of two triad aromatic ester type mesogenic moieties connected via polymethylene spacers were synthesized and their liquid crystalline properties compared. The two mesogenic units are connected in either Hor T-shape or in linear fashion. In general, it was found that mesophase temperature ranges for the T- and linear-shaped compounds are much wider than for the H-shaped compounds. Moreover, the former are enantiotropic thermotropic materials, whereas the latter tend to be monotropic unless the spacer length is fairly long, i.e. longer than decamethylene. Among the three series, the linearly linked twin compounds had the highest melting and isotropization temperatures. All of the linear and T-shaped dimeric compounds reported in this article form only nematic mesophases.