Structure of dichlorine monoxide as studied by microwave spectroscopy. Determination of equilibrium structure by a modified mass dependence method |
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Authors: | Munetaka Nakata Masaaki Sugie Harutoshi Takeo Chi Matsumura Tsutomu Fukuyama Kozo Kuchitsu |
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Institution: | 1. National Chemical Laboratory for Industry, Yatabe, Tsukuba-gun, Ibaraki 305, Japan;2. Department of Chemistry, Faculty of Science, The University of Tokyo, Bunkyo-ku, Tokyo 113, Japan |
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Abstract: | The microwave spectra of four isotopic species of dichlorine monoxide (OCl2) have been observed, and the rotational constants have been obtained. The rm structure for each isotopic species has been determined by Watson's method. The equilibrium structure has been estimated by taking proper averages of rm structures to be and ∠eClOCl = 110.886(6)°. The general applicability and the merit of the present method for estimating the equilibrium structure are pointed out. |
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