Absorption spectrum of trideuteromethane between 7 and 11 μm. Analysis of the ν5 band

The absorption spectrum of trideuteromethane was recorded in the range 900–1400 cm^?1 with a resolution of 0.020–0.025 cm^?1. The ν₅ band centered at 1292.499 cm^?1 is analyzed here. A fit based on 869 observed transitions including J′ values up to 22, leads to a set of spectroscopic constants suitable for energy calculations in the upper-state v₅ = 1. These constants reproduce the experimental wavenumbers with a standard deviation equal to 0.008 cm^?1. The tabulated line strengths are calculated on the basis of the value S = 27.1 cm^?2 atm^?1 at 300 K, measured by Hiller and Straley, for the band strength of ν₅. A useful comparison is made between the values now derived for some constants and the corresponding ones predicted by Gray and Robiette in their recent force field calculations of methane and isotopic species.