Templated dynamic cryptophane formation in water |
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Authors: | Givelet Cécile Sun Junling Xu Di Emge Thomas J Dhokte Ashwini Warmuth Ralf |
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Institution: | Rutgers, The State University of New Jersey, Department of Chemistry and Chemical Biology, 610 Taylor Road, Piscataway, NJ 08817, USA. |
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Abstract: | Several dynamic hexaimine cryptophanes, that are built up from two triformylcyclotribenzylene cavitands and three diamino linkers and spontaneously assemble in water in the presence of a suitable templating guest, are reported. X-ray structure, kinetics and thermodynamics of assembly and molecular recognition properties are discussed. |
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