Surface friction of thermoresponsive poly(N-isopropylacrylamide) gels in water |
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Authors: | Atsushi Suzuki Ryota Ishii Yoji Yamakami Ken Nakano |
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Institution: | 1. Faculty of Environment and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, 240-8501, Yokohama, Japan
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Abstract: | In this paper, we report the experimental results of surface friction between thermoresponsive poly(N-isopropylacrylamide) gels in water. The static friction force was found to depend on the waiting period prior to slider movement after contact between gel surfaces, which was a result of two relaxation mechanisms: the stress decay process due to macroscopic deformation under a normal load and the microscopic conformational change in the real contact area of polymer networks. The sliding velocity and the normal load dependence of the kinetic friction force were extensively measured. The results suggested that the following two mechanisms depended on the sliding velocity: the friction force generated by direct contact of the solid-like behavior and the viscous resistance of the liquid-like behavior. The strong temperature dependence of kinetic friction was observed, which was a result of a change in the balance between hydrophobic and hydrophilic interactions. The experimental results are discussed in terms of the multi-asperity contacts between the swollen gel/gel interfaces (solid friction, depending on the waiting period) and the viscous resistance and lubricating effect between the gel/water interfaces (fluid friction, depending on the sliding velocity). |
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