| Abstract: | A facile and electrostatically driven approach has been developed to prepare bicontinuous polymer nanocomposites that is based on the polyoxometalate (POM) macroion induced phase transition of PS‐b ‐P2VP from an initial lamellar phase to a stable bicontinuous phase. The multi‐charged POMs can electrostatically cross‐link P2VP blocks and give rise to bicontinuous phases in which the POM hybrid conductive domains occupy a large volume fraction of more than 50 %. Furthermore, the POMs can give rise to high proton conductivity and serve as nanoenhancers, endowing the bicontinuous nanocomposites with a conductivity of 0.1 mS cm−1 and a Young's modulus of 7.4 GPa at room temperature; these values are greater than those of pristine PS‐b ‐P2VP by two orders of magnitude and a factor of 1.8, respectively. This approach can provide a new concept based on electrostatic control to design functional bicontinuous polymer materials. |
