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Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3)−H Bond Activation |
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| Abstract: | A palladium‐catalyzed reaction of primary amines with iodoarenes produces γ‐arylated primary amines. A bulky salicylaldehyde, which is marked as easily available, installable, removable, and recoverable, plays a key role in directing palladium to site‐selectively activate the C−H bond located γ to the amino group. |
| Keywords: | Amine Arylierungen C-H-Aktivierung Palladium Reaktionsmechanismen |