| Abstract: | Polymer electrolyte membranes employed in contemporary fuel cells severely limit device design and restrict catalyst choice, but are essential for preventing short‐circuiting reactions at unselective anode and cathode catalysts. Herein, we report that nickel sulfide Ni3S2 is a highly selective catalyst for the oxygen reduction reaction in the presence of 1.0 m formate. We combine this selective cathode with a carbon‐supported palladium (Pd/C) anode to establish a membrane‐free, room‐temperature formate fuel cell that operates under benign neutral pH conditions. Proof‐of‐concept cells display open circuit voltages of approximately 0.7 V and peak power values greater than 1 mW cm?2, significantly outperforming the identical device employing an unselective platinum (Pt) cathode. The work establishes the power of selective catalysis to enable versatile membrane‐free fuel cells. |
