Phase‐Selective Syntheses of Cobalt Telluride Nanofleeces for Efficient Oxygen Evolution Catalysts

Cobalt‐based nanomaterials have been intensively explored as promising noble‐metal‐free oxygen evolution reaction (OER) electrocatalysts. Herein, we report phase‐selective syntheses of novel hierarchical CoTe₂ and CoTe nanofleeces for efficient OER catalysts. The CoTe₂ nanofleeces exhibited excellent electrocatalytic activity and stablity for OER in alkaline media. The CoTe₂ catalyst exhibited superior OER activity compared to the CoTe catalyst, which is comparable to the state‐of‐the‐art RuO₂ catalyst. Density functional theory calculations showed that the binding strength and lateral interaction of the reaction intermediates on CoTe₂ and CoTe are essential for determining the overpotential required under different conditions. This study provides valuable insights for the rational design of noble‐metal‐free OER catalysts with high performance and low cost by use of Co‐based chalcogenides.