Mass spectrometry of steroid systems—XXI Appearance and ionization potentials for the stereo-isomers of the D-homoestrane series |
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Authors: | V. I. Zaretskii V. L. Sadovskaya N. S. Wulfson V. F. Sizoy V. G. Merimson |
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Affiliation: | Institute for Chemistry of Natural Products, USSR Academy of Sciences, Moscow, USSR |
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Abstract: | The ionization potentials of methyl ethers of D-homoequilenine, its 14ß-isomer, D-homoestrone and its 8°-isomer, as well as appearance potentials of certain fragment ions have been determined by means of electron-impact. The dissociation energies of the bonds which are split in the course of formation of these ions have been calculated. |
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