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Hydroxylation and epoxidation studies of some 3,4-dialkylcyclopentenes
Authors:R. Hanselaer  M. Samson  M. Vandewalle
Affiliation:Department of Organic Chemistry, State University of Ghent, Laboratory for Organic Synthesis, Krijgslaan, 271 (S.4), B-9000 Gent, Belgium
Abstract:The hydroxylation and the epoxidation of the cis and trans isomers of 3,4-dimethylcyclopentene and 4-t-butyl-3-methylcyclopentene have been studied. The stereoselectivity was studied as a function of the basic conformation of the individual cyclopentenes; the conformations were determined by 1H NMR spectroscopy.
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