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On the estimation of the reaction mechanisms of thermal decomposition of solids from the fraction reacted at the maximum reaction rate
Authors:JM Criado  R Garcia-Rojas  J Morales
Institution:Departamento de Quimica Inorgánica, Facultad de Ciencias de la Universidad de Sevilla, Sevilla Spain;Departamento de Investigaciones Fisicas y Quimicas, Centro Coordinado del C.S.I.C., Sevilla Spain
Abstract:A procedure is developed for determining equilibrium constants of reactions of the type: A (solid) ? B (solid) + C (gas) from TG data. The method is based upon the overlapping of both formation and decomposition TG diagrams when an appropriate heating rate is applied.
Keywords:
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