On the estimation of the reaction mechanisms of thermal decomposition of solids from the fraction reacted at the maximum reaction rate |
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Authors: | JM Criado R Garcia-Rojas J Morales |
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Institution: | Departamento de Quimica Inorgánica, Facultad de Ciencias de la Universidad de Sevilla, Sevilla Spain;Departamento de Investigaciones Fisicas y Quimicas, Centro Coordinado del C.S.I.C., Sevilla Spain |
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Abstract: | A procedure is developed for determining equilibrium constants of reactions of the type: A (solid) ? B (solid) + C (gas) from TG data. The method is based upon the overlapping of both formation and decomposition TG diagrams when an appropriate heating rate is applied. |
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