The chemistry of uranium Part XXI. A thermogravimetric study of the decomposition of (Net4)2UCl6 and (Net4)2UBr6 |
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Authors: | JGH du Preez CPJ van Vuuren |
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Institution: | Uranium Chemistry Research Unit, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth, 6000 South Africa |
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Abstract: | The thermal decomposition reactions of (Net4)2UX6, X = Cl, Br, were studied in nitrogen and oxygen atmospheres. Isothermal and dynamic techniques were used to estimate activation energies for the reactions in nitrogen. The bromo complex seems to be more resistant towards decomposition than the chloro complex. |
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