Études calorimétriques en milieu solvant organique: III. Enthalpie de dilution de l'alanate de lithium LiAlH4 dans le tétrahydrofuranneen présence d'halogénure de lithium |
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Authors: | Pierre Claudy Bernard Bonnetot Daniel Mathurin Guy Turck |
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Affiliation: | Laboratoire de Physico-Chimie Minérale associé au C.N.R.S. no 116 I.N.S.A., 20, avenue Albert Einstein, 69621 Villeurbanne Cedex France |
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Abstract: | Heats of dilution of lithium aluminum hydride in THF, in THFLiBr and in THFLiCl have been established. At a constant concentration of LiBr in THF, dilution of LiAlH4 is exothermal, and consequently it is shown that lithium aluminum hydride is dissociated in THF. |
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