Heats of mixing of 2,2-dimethoxypropane and diethoxymethane with some 1-alkenes |
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Authors: | Roger Meyer Gerard Giusti |
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Institution: | Laboratoire de Chimie Organique Physique, Faculté des Sciences et Techniques de Saint-Jérōme, Av. H. Poincaré 13397, Marseille Cédex 4 France |
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Abstract: | The excess enthalpies of 2,2-dimethoxypropane + 1-hexene, + 1-heptene and + 1-octene, and of diethoxymethane + 1-hexene + 1-octene have been measured at 298.15 K. The values of HE for all the systems are positive and increase with increasing chain length of the alkene. The results are analysed in term of the quasi-lattice theory of mixtures using the zeroth approximation. |
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Keywords: | To whom all correspondence should be addressed |
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