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金属锂在含多硫化物电解液中的稳定性研究
引用本文:王梦佳,赵春荣,王维坤,余仲宝,王安邦,苑克国,黄雅钦.金属锂在含多硫化物电解液中的稳定性研究[J].北京化工大学学报(自然科学版),2013,40(5):34-38.
作者姓名:王梦佳  赵春荣  王维坤  余仲宝  王安邦  苑克国  黄雅钦
作者单位:北京化工大学材料科学与工程学院,北京,100029;防化研究院军用化学电源研究与发展中心,北京,100191
基金项目:国家“863”计划(2012AA052202)
摘    要:采用交流阻抗法、循环伏安法对金属锂在含多硫化物电解液和不含多硫化物电解液中生成的表面固体电解质界面膜(SEI膜)的稳定性进行了研究。结果表明,与在不含多硫化物电解液中形成的SEI膜相比,金属锂在含多硫化物电解液中形成的SEI膜更稳定,导电性更好,多次循环后金属锂表面没有明显的枝晶、粉化发生,金属锂在含多硫化物电解液中的交换电流密度和充放电效率更高。

关 键 词:锂-硫二次电池  金属锂  固体电解质界面膜  稳定性
收稿时间:2013-04-03

Stability of the lithium metal in an electrolyte containing polysulfides
WANG MengJia;ZHAO ChunRong;WANG WeiKun;YU ZhongBao;WANG AnBang;YUAN KeGuo;HUANG YaQin.Stability of the lithium metal in an electrolyte containing polysulfides[J].Journal of Beijing University of Chemical Technology,2013,40(5):34-38.
Authors:WANG MengJia;ZHAO ChunRong;WANG WeiKun;YU ZhongBao;WANG AnBang;YUAN KeGuo;HUANG YaQin
Institution:1.College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029; 2.Military Power Sources Research and Development Center, Research Institute of Chemical Defense, Beijing 100191, China
Abstract:The stability of lithium solid electrolyte interface(SEI)membranes in different electrolytes has been investigated using AC impedance and cyclic voltammetry methods. The results showed that the lithium SEI membranes formed in an electrolyte containing polysulfide anions were more stable than those formed in a conventional electrolyte, and also had better electrical conductivity. Furthermore, after several cycles, the lithium metal showed no obvious dendrite formation or pulverization in the electrolyte containing polysulfides. The kinetic performance of the lithium metal in the electrolyte containing polysulfides was also better than that in a conventional electrolyte.
Keywords:
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