Solvent Effect on the Partial Molar Volume and the Enthalpy of Solution of Gallium Chloride |
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| Authors: | Kiselev S. V. Kashaeva E. A. Konovalov A. I. |
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| Affiliation: | (1) Butlerov Research Chemical Institute, Kazan State University, Kazan, Tatarstan, Russia |
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| Abstract: | Partial molar volumes and heats of solution were determined for gallium chloride in benzene, toluene, o-xylene, mesitylene, 1,2-dichloroethane, ethyl acetate, acetonitrile, and 1,4-dioxane. A proportionality in changes in these characteristics is observed for weak  , -type complexes in alkylbenzene medium. The partial molar volumes of strong n,-type complexes approach a limiting value. |
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