Determination of the pesticide Chlorpyrifos by cathodic adsorptive stripping voltammetry |
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Authors: | M. S. El-Shahawi M. M. Kamal |
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Affiliation: | Department of Chemistry, Faculty of Science at Damiatta, Mansoura University, Damiatta, Egypt, EG Department of Chemistry, Faculty of Science, Assiut University, Assiut, Egypt, EG
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Abstract: | The adsorption behavior and differential pulse cathodic adsorptive stripping voltammetry of the pesticide Chlorpyrifos (CP) were investigated at the hanging mercury drop electrode (HMDE). The pesticide was accumulated at the HMDE and a well-defined stripping peak was obtained at –1.2 V vs Ag/AgCl electrode at pH 7.50. A voltammetric procedure was developed for the trace determination of Chlorpyrifos using differential pulse cathodic adsorptive stripping voltammetry (DP-CASV). The optimum working conditions for the determination of the compound were established. The peak current was linear over the concentration range 9.90 × 10–8– 5.96 × 10–7 mol/L of Chlorpyrifos. The influence of diverse ions and some other pesticides was investigated. The analysis of Chlorpyrifos in commercial formulations and treated waste water was carried out satisfactorily |
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