[Fe(phen)3]2+ aquation in aqueous polyacrylamide solution |
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Authors: | H D Burrows J Ige and L O Oyewumi |
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Institution: | (1) Chemistry Department, Obafemi Awolowo University, Ile-Ife, Nigeria;(2) Present address: Departamento de Química, Universidade de Coimbra, 3049 Coimbra, Portugal |
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Abstract: | The aquation of tris(1, 10-phenanthroline) iron(II) has been studied in aqueous polyacrylamide solutions. The rate increases up to 2.8 times at low polymer concentrations, and subsequently decreases. These effects are attributed to changes in the local water activity in the region of the complex.
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