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表面等离子体共振光谱技术与电化学方法联用及其应用
引用本文:包宇,毛燕,王伟,李正刚,牛利. 表面等离子体共振光谱技术与电化学方法联用及其应用[J]. 电化学, 2013, 19(1): 17-28
作者姓名:包宇  毛燕  王伟  李正刚  牛利
作者单位:中国科学院长春应用化学研究所,现代分析技术工程实验室,吉林 长春 130022
基金项目:国家自然科学基金委仪器专项(No.20827004)资助
摘    要:表面等离子体共振(Surface Plasmon Resonance,SPR)技术是利用金属薄膜光学耦合产生的物理光学现象建立的一种非常灵敏的光学分析手段. 近年发展的电化学表面等离子体共振(Electrochemical Surface Plasmon Resonance,EC-SPR)是将时间分辨表面等离子体共振光谱技术与电化学方法联用的一种新技术. 本文介绍了SPR和EC-SPR的基本原理,并重点阐述了时间分辨SPR光谱技术与电化学方法联用及应用,该技术已广泛地应用于反应动态过程研究、生物化学传感器、电极/溶液界面的表征、动力学常数的测定以及生物分子相互作用等领域.

关 键 词:表面等离子体共振  时间分辨等离子体共振光谱技术  电化学  电化学表面等离子体共振  
收稿时间:2011-11-09

Combination and Applications of Time-Resolved Surface Plasmon Resonance Spectroscopy and Electrochemical Methods
BAO Yu,MAO Yan,WANG Wei,LI Zheng-gang,NIU Li. Combination and Applications of Time-Resolved Surface Plasmon Resonance Spectroscopy and Electrochemical Methods[J]. Electrochemistry, 2013, 19(1): 17-28
Authors:BAO Yu  MAO Yan  WANG Wei  LI Zheng-gang  NIU Li
Affiliation:1(1.State Key Laboratory of Electroanalytical Chemistry,Engineering Laboratory for Modern Analytical Techniques,Changchun Institute of Applied Chemistry,Changchun 130022,China; 2.Graduate University of the Chinese Academy of Sciences,Beijing 100049,China)
Abstract:Electrochemical-surface plasmon resonance (EC-SPR) technique, developed in recent years, is a new technology which combines time-resolved surface plasmon resonance spectroscopy and electrochemical methods. Surface plasmon resonance (SPR) is a physical phenomenon generated by optical coupling using a metallic thin film and is very sensitive to optical analysis. The principles of SPR and EC-SPR are briefly introduced and the applications of the combination of SPR spectroscopy with electrochemical techniques are reviewed in this paper. This new technology has been widely used in such research areas as reaction dynamics, biochemical sensors, electrode/electrolyte interfaces, kinetic parameters and bimolecular interactions.
Keywords:surface plasmon resonance  high time-resolved surface plasmon resonance  electrochemistry  electrochemical surface plasmon resonance  
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