Synthesis and properties of biodegradable polycaprolactone/polyurethanes using fluoro chain extenders |
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Authors: | Cheng‐Lung Wu Shih‐Hsuan Chiu Hsun‐Tsing Lee Maw‐Cherng Suen |
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Institution: | 1. Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei, Taiwan;2. Department of Materials Science and Engineering, Vanung University, Jongli, Taoyuan, Taiwan;3. Department of Creative Fashion Design, Taoyuan Innovation Institute of Technology, Jongli, Taoyuan, Taiwan |
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Abstract: | In this study, biodegradable fluorine‐containing polyurethanes (PU/OFHD) were synthesized using 4,4'‐diphenylmethane diisocyanate, polycaprolactone diol (PCL), and 2,2,3,3,4,4,5,5,‐octafluoro‐1,6‐hexanediol (OFHD). PCL is a biodegradable soft segment, and OFHD is a fluoro chain extender. In addition, other polyurethanes (PU/HD) were synthesized using 4,4'‐diphenylmethane diisocyanate, PCL, and another chain extender i.e., 1,6‐hexanediol (HD)] for comparison. Gel permeation chromatography analysis indicated that the molecular weight of PU/OFHD is greater than that of PU/HD. 19F nuclear magnetic resonance analysis revealed that the OFHD chain extender was successfully incorporated into the backbone of PU. According to Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy analyses, strong interactions between the C=O and CF2 groups in PU/OFHD exist. Based on thermal analysis, PU/OFHD exhibited an initial decomposition temperature that was 6.5–7.9°C higher than that of PU/HD. Differential scanning calorimetry and dynamic mechanical analysis analyses indicated that both the glass transition (Tg) and dynamic Tg of PU/OFHD are higher than those of PU/HD. Mechanical property analysis demonstrated that the tensile strength of PU/OFHD is higher than that of PU/HD. Moreover, PU/OFHD exhibited better chemical resistance than PU/HD. The scanning electron microscope images indicated that both PU/HD and PU/OFHD exhibited higher hydrolytic degradation at a higher PCL content. However, PU/OFHD is less degradable than PU/HD. Copyright © 2015 John Wiley & Sons, Ltd. |
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Keywords: | polyurethanes hydrogen bonding chemical resistance hydrolytic degradation |
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